Hi! Welcome to Kazakhstan!
It is very wise of you to get prepared to the winter. Cause it is very freezing!
As I'm a wife of my business man I can tell how usually he goes outside when going to office. In December it is always very windy. So, yes you will need hooded overcoat and really thick! Wind and water protected, please!
Boots must be very protected! My husband wears Timberland's boots, they are very warm and protected. But of course they are mostly for casual wear. Regarding office wear, usually it's leather boots with fleece. And he has normal shoes to change in the office. I don't know if it is a habit in every office. Thermo underwear will be perfect too:)
Head have to be covered. If you'd like you can buy a fur hat in stores of Astana. There are pretty good variety of them.
This is what I know and would recommend for sure!

Good luck with preparations!
Cheers!

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